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Creators/Authors contains: "Martin, Caleb D"

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  1. The selective 1,4-bromoboration of nitroalkenes occurs under mild conditions with a bromoborane featuring two 1-methyl-ortho-carborane substituents, BrBMeoCb2
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  2. The dearomative functionalization of indoles to C2-borylated indolenium compounds is achieved under mild conditions by leveraging the high Lewis acidity of bis(1-methyl-ortho-carobranyl)borane. 
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  3. This perspective covers the 99 years of work towards the isolation of a cyclopentadienyl cation, from observation of fleeting compounds to the 2024 X-ray crystal structure of a room temperature stable Cp+cation. 
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  4. Bis(1-methyl-ortho-carboranyl)borane reacts with PPh3Au acetylide to give an η2-1-borataallene Au complex while the Cu acetylide furnishes a CuPPh3+alkynylborate complex with a hydride bridging boron to copper. 
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  5. Phenanthrylboroles with 3,4-conjugation have been synthesized which react with azides to furnish B,N-pyrene analogues. 
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