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Creators/Authors contains: "Martin, Caleb D"

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  1. The dearomative functionalization of indoles to C2-borylated indolenium compounds is achieved under mild conditions by leveraging the high Lewis acidity of bis(1-methyl-ortho-carobranyl)borane. 
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    Free, publicly-accessible full text available April 1, 2026
  2. This perspective covers the 99 years of work towards the isolation of a cyclopentadienyl cation, from observation of fleeting compounds to the 2024 X-ray crystal structure of a room temperature stable Cp+cation. 
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    Free, publicly-accessible full text available January 29, 2026
  3. Free, publicly-accessible full text available January 1, 2026
  4. Phenanthrylboroles with 3,4-conjugation have been synthesized which react with azides to furnish B,N-pyrene analogues. 
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  5. Carborane fused boron doped polycyclic aromatic hydrocarbons were accessed by dehydrobrominative and dehydrogenative borylation. 
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  6. The additions of the phosphinoboronate ester Ph2PBpin to an antiaromatic borole and a borafluorene is reported. The Lewis acid/base adducts are obtained in excellent yields and represent the first P-donor adducts of Ph2PBpin. 
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  7. Reactions of tris(ortho-carboranyl)borane with Lewis bases reveals only small bases bind. The tremendous bulk and Lewis acidity is leveraged in frustrated Lewis pair Si–H cleavage with a wider range of Lewis bases and greater efficacy than B(C6F5)3
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